We are currently interested in developing a series of networks and clusters using a synthetic methodology known as a building block approach. This methodology utilizes a series of robust molecular precursors that self-assemble with their structures intact, into well-defined structural archetypes. Through substitution of the building blocks employed, a series of structurally related clusters and networks may be engineered that exhibit a variety of tunable properties. Among these are dramatic color changes and magnetism upon the application of various external stimuli. Once prepared the properties of these solids are investigated via a variety of physical (spectroscopic and magnetic), photophysical, and structural determination methods (X-ray).
If you would like to learn more about currently funded projects please click the link above. For available undergraduate, graduate, and postdoctoral positions please contact Stephen M. Holmes at holmesst@umsl.edu.